Reductive Dechlorination of 1,1,2,2-Tetrachloroethane

Kinetics of Reductive Dechlorination of Trichloroethane (TeA) by Anaerobic Biofilms

A New Electron Donor for Reductive Dechlorination of Perchloroethylene

One of the main problems associated with remediation of chlorinated solvent groundwater contamination is the presence of NAPLs in the source zone. NAPLs are often better treated through solvent extraction, surfactant washing, or vapor extraction than through bioremediation. Removal of NAPL through solvent extraction would likely leave a substantial residual of both the extraction solvent and th...

Acetylene Inhibition of Trichloroethene and Vinyl Chloride Reductive Dechlorination

Kinetic studies reported here have shown that acetylene is a potent reversible inhibitor of reductive dehalogenation of trichloroethene (TCE) and vinyl chloride (VC) by a mixed dehalogenating anaerobic culture. The mixed culture was enriched from a contaminated site in Corvallis, OR, and exhibited methanogenic, acetogenic, and reductive dehalogenation activities. The H2-fed culture transformed ...

Abiotic reductive dechlorination of chlorinated ethylenes by soil.

Abiotic reductive dechlorination of chlorinated ethylenes by soil in anaerobic environments was characterized to improve knowledge of the behavior of chlorinated ethylenes in natural systems, including systems modified to promote attenuation of contaminants. Target organics in the soil suspension reached sorption equilibrium in 2 days and the sorption isotherm of target organics was properly de...

Regiospecificity of chlorophenol reductive dechlorination by vitamin b(12s).

Vitamin B(12), reduced by titanium (III) citrate to vitamin B(12s), catalyzes the reductive dechlorination of chlorophenols. Reductive dechlorination of pentachlorophenol and of all tetrachlorophenol and trichlorophenol isomers was observed. Reaction of various chlorophenols with vitamin B(12) favored reductive dechlorination at positions adjacent to another chlorinated carbon, but chlorines or...